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Enantiospecific total synthesis of both enantiomers of 2-thiocyanatoneopupukeanane from (R)-carvone

Srikrishna, A and Gharpure, Santosh J (2000) Enantiospecific total synthesis of both enantiomers of 2-thiocyanatoneopupukeanane from (R)-carvone. In: Journal of The Chemica Society -Perkin Transaction 1 (19). pp. 3191-3193.

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Official URL: http://www.rsc.org/publishing/journals/P1/article....

Abstract

Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanane starting from (R)-carvone, employing an intramolecular rhodium carbenoid C-H insertion reaction as the key step, is described.

Item Type: Journal Article
Publication: Journal of The Chemica Society -Perkin Transaction 1
Publisher: Royal Society of Chemistry
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 03 Jun 2009 06:25
Last Modified: 03 Jun 2009 06:25
URI: http://eprints.iisc.ac.in/id/eprint/18463

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