An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate

Ravikumar, KS and Chandrasekaran, S (1997) An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate. In: Tetrahedron, 53 (8). pp. 2973-2978.

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Abstract

Titanium(III) Tetrahydroborate formed in situ from titanium tetrachloride and benzyltrieihylammonium retrahydroborate (1:4) readily reacts with cyclic enol ethers in dichloromethane at -20 degrees C to give the corresponding acyclic diols in high yields after simple aqueous work-up.

Item Type:	Journal Article
Publication:	Tetrahedron
Publisher:	Elsevier Science
Additional Information:	Copyright of this article belongs to Elsevier Science.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	08 Feb 2010 06:30
Last Modified:	19 Sep 2010 05:01
URI:	http://eprints.iisc.ac.in/id/eprint/18397

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