Prabhu, KR and Sivanand, PS and Chandrsekaran, S (1998) A new methodology for the reductive cyclization of omega-azido carbonyl compounds mediated by tetrathiomolybdate: Application to an efficient synthesis of pyrrolo[2,1-c][1,4]benzodiazepines. In: Synlett (1). pp. 47-48.
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Abstract
The omega-azido carbonyl compounds on treatment with tetrathiomolybdate, 1 led to the formation of 5, 6 and 7 membered cyclic imines in very good yields under mild conditions. This method is applied successfully to a new efficient synthesis of 1,4-benzodiazapinone derivatives and in particular Bzl DC-81.
| Item Type: | Journal Article |
|---|---|
| Publication: | Synlett |
| Publisher: | Thieme Medical Publishers |
| Additional Information: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | tetrathiomolybdate;omega-azidocarbonyl compounds;reductive cyclization;pyrrolobenzodiazepines. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 13 Nov 2009 06:08 |
| Last Modified: | 13 Nov 2009 06:08 |
| URI: | http://eprints.iisc.ac.in/id/eprint/17980 |
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