Kulkarni, GV (1986) Cluster approach to chemisorption and electrochemisorption -a critique. In: Indian Journal of Technology, 24 (8). pp. 457-464.
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The problem of chemisorption, especially in the electrochemical context, was analyzed based on the cluster approach. In this approach the metal surface is represented by a set of atoms in their bulk superimposable surface geometry. Reasonably good description of the interactions at the electrode can be obtained by using the HOMO-LUMO picture of the electrode, adspecies, and solvent. The effect of applied potential (anodic/cathodic) on electrochemisorption is simulated by appropriate Fermi level shifts of the electrode. This could be a 1st step towards a unified MO approach to electrochemical surface science.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Technology |
| Publisher: | Council of Scientific & Industrial Research (India) |
| Additional Information: | Copyright for this article belongs to Council of Scientific & Industrial Research (India) |
| Keywords: | Cluster approach;chemisorption;electrochemisorption |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 04 Aug 2008 |
| Last Modified: | 27 Aug 2008 13:39 |
| URI: | http://eprints.iisc.ac.in/id/eprint/15361 |
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