Proton and Carbon-13 Nuclear Magnetic Resonance Studies of Conformations of 1,3-Dipyridylthioureas

Sudha, Lalgudi V and Sathyanarayana, Dixit N (1986) Proton and Carbon-13 Nuclear Magnetic Resonance Studies of Conformations of 1,3-Dipyridylthioureas. In: Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 11 . pp. 1647-1650.

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Abstract

Studies of $^1H$ and $^{13}C$ chemical shifts and of $^1H-^lH$, $^{l3}C-^1H$ coupling constants of 1,3-di-(2-pyridyl)- thiourea and its substituted derivatives indicate the occurrenceof topomerisation between two internally hydrogen-bonded conformers, with a Z,E \rightleftharpoons E,Z interconversion barrier of ca. $55.0 kJ mol^{-l}$.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999)
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright to this article belongs to Royal Society of Chemistry.
Keywords:	Proton;carbon-13;magnetic resonance;conformations;dipyridylthioureas
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	01 Jul 2008
Last Modified:	19 Sep 2010 04:46
URI:	http://eprints.iisc.ac.in/id/eprint/14699

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