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Kinetics of the Aminolysis Reactions of Chlorocyclotriphosphazenes - Change-over from a $S_N2$(P) to a $S_N1$(P) mechanism

Katti, KV and Krishnamurthy, SS (1983) Kinetics of the Aminolysis Reactions of Chlorocyclotriphosphazenes - Change-over from a $S_N2$(P) to a $S_N1$(P) mechanism. In: Phosphorus and Sulfur and the Related Elements, 14 (2). pp. 157-159.

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Abstract

A change-over from $S_N2$(P) to $S_N1$(P) mechanism is established for the chlorine replacement reactions of halogenocyclophosphazenes; this mechanistic change-over helps in rationalising the diverse findings reported for this class of reactions.

Item Type: Journal Article
Publication: Phosphorus and Sulfur and the Related Elements
Publisher: Taylor & Francis
Additional Information: Copyright of this article belongs to Taylor & Francis.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 16 Jun 2008
Last Modified: 27 Aug 2008 13:28
URI: http://eprints.iisc.ac.in/id/eprint/14420

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