Gajapathy, D and Govindarajan, S and Patil, KC and Manohar, H (1983) Synthesis, Characterisation and Thermal Properties of Hydrazinium Metal Oxalate Hydrates. Crystal and Molecular Structure of Hydrazinium Copper Oxalate Monohydrate. In: Polyhedron, 2 (9). pp. 865-873.
![]() |
PDF
3.pdf Restricted to Registered users only Download (678kB) | Request a copy |
Abstract
Complexes of the formula $(N_2H_5)_2M(C_2O_4)_2.nH_2O$ M = Co, Ni, Cu, n = 3, 2, 1 respectively have been prepared and their spectral, magnetic and thermal properties investigated. The copper complex, $(N_2H_5)_2Cu(C_2O_4)_2.H_2O$.$H_20$ has a square planar geometry with no coordination of hydrazinium cations as confirmed by a single crystal X-ray study. Nickel and cobalt form octahedral complexes and X-ray powder patterns reveal that the complexes are not isomorphous.
Item Type: | Journal Article |
---|---|
Publication: | Polyhedron |
Publisher: | Elsevier |
Additional Information: | Copyright belongs to Elsevier. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 18 Jun 2008 |
Last Modified: | 19 Sep 2010 04:46 |
URI: | http://eprints.iisc.ac.in/id/eprint/14401 |
Actions (login required)
![]() |
View Item |