Navaneetham, NS and Rajasekar, N and Kalyanasundaram, R and Soundararajan, S (1987) Lanthanide Perchlorate Complexes of 4-Chloroquinoline-1-oxide and 5-Chloroisoquinoline-2-oxide. In: Inorganica Chimica Acta, 128 (2). pp. 277-282.
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Abstract
New lanthanide complexes of 4-chloroquinoline-1-oxide (CQNO) and 5-chloroisoquinoline-2-oxide (CIQNO) were synthesized. CQNO gave two sets of complexes, one set soluble in acetone with the formulae {[Ln(CQNO)_8](ClO_4)_3}, where Ln=Nd to Yb, and {[La(CQNO)_{10}]}{(ClO_4)_3}, and the other insoluble in acetone with the formulae {[Ln(CQNO)_7]- (ClO_4)_3} where Ln=La, Nd and Gd only. CIQNO gave complexes of the general composition {[Ln-(CIQNO)_8](ClO_4)_3} where Ln =La and Nd and {[Ln(CIQNO)_7](ClO_4)_3} where Ln=Gd to Yb. The isolated complexes CQNO and CIQNO were characterized by elemental analysis, electrolytic conductance, infrared, proton NMR and electronic spectral data.
Item Type: | Journal Article |
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Publication: | Inorganica Chimica Acta |
Publisher: | Elsevier |
Additional Information: | Copyright for this article belongs to the Elsevier. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 13 Jun 2008 |
Last Modified: | 07 Oct 2010 07:16 |
URI: | http://eprints.iisc.ac.in/id/eprint/14303 |
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