Usha, MG and Rao, Subba M and Kutty, Narayanan TR (1986) Preparation and thermal stability of ammonium alkaline earth trioxalatocobaltate(III) hydrates:$NH_4M^{2+}[Co(C_2O_4)_3].xH_2O$. In: Journal of Thermal Analysis and Calorimetry, 31 (1). pp. 7-14.
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$NH_4M^{2+}[Co(C_2O_4)_3].xH_2O (M^{2+} = Ba, Sr and Ca)$ were prepd. and characterized and their thermal behavior studied. The compounds. decompose in a complex manner to yield bivalent metal carbonate or oxide and Co oxide as final products. The formation of the final products is affected by the surrounding atmosphere during decomposion $M^{2+}CoO_{3-x}$ was not identified among the final products of decomposion This study demonstrates the importance of the decomposion mode of the precursor in producing the desired end-product.
| Item Type: | Journal Article |
|---|---|
| Publication: | Journal of Thermal Analysis and Calorimetry |
| Publisher: | Akadémiai Kiadó, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic Publishers B.V. |
| Additional Information: | Copyright belongs to Akadémiai Kiadó, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic Publishers B.V. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 07 May 2008 |
| Last Modified: | 27 Aug 2008 13:21 |
| URI: | http://eprints.iisc.ac.in/id/eprint/13851 |
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