Jain, SR and Mimani, T (1990) Temperature profiles of reactive biliquid systems prior to ignition. In: Journal of Thermal Analysis and Calorimetry, 36 (7-8). pp. 2393-2406.
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Abstract
A thin-film thermometric device was used to record the temperature profiles of the exothermic reactions occurring between various substituted benzenes and anhydrous nitric acid. A comparison of the profiles indicated that the extent of exothermicity and the rate of heat evolution depend on the substituent/s on the benzene ring. The initial reaction was identified as nitration, which is accompanied by other exothermic reactions, especially in systems leading to ignition. The profiles of the self-igniting systems, amine-$HNO_3$ and amine-$N_2O_4$, suggest that, apart from their individual exothermicities, the specific nature of the fuel-oxidizer reaction also plays an important role in the onset of ignition.
Item Type: | Journal Article |
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Publication: | Journal of Thermal Analysis and Calorimetry |
Publisher: | Akadémiai Kiadó |
Additional Information: | Copyright of this article belongs to Akadémiai Kiadó. John Wiley & Sons, Limited, Chichester is the publisher of English version. |
Keywords: | thin-film;thermometric device;exothermic reaction;fuel-oxidizer reaction |
Department/Centre: | Division of Mechanical Sciences > Aerospace Engineering(Formerly Aeronautical Engineering) |
Date Deposited: | 27 Dec 2007 |
Last Modified: | 19 Sep 2010 04:41 |
URI: | http://eprints.iisc.ac.in/id/eprint/12586 |
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