A novel one-pot metathesis route for the synthesis of double perovskites, $Ba_3MM'2O_9 (M = Mg, Ni, Zn; M' = Nb, Ta)$ with 1 : 2 ordering of M and M' atoms

Mani, Rohini and Bhuvanesh, NSP and Ramanujachary, KV and Green, William and Lofland, SE and Gopalakrishnan, J (2007) A novel one-pot metathesis route for the synthesis of double perovskites, $Ba_3MM'2O_9 (M = Mg, Ni, Zn; M' = Nb, Ta)$ with 1 : 2 ordering of M and M' atoms. In: Journal of Marterials Chemistry, 17 (16). pp. 1589-1592.

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Abstract

Solid state reaction of $Li_2CO_3$, $MC_2O_4.2H_2O(M = Mg, Ni,Zn)$, $M'_2O_5 (M' = Nb, Ta)$ and $BaCl_2$ in stoichiometric quantities at $900-1100^o C$ in air provides a convenient one-pot synthesis route for 1 : 2 B-site ordered double perovskite oxides, $Ba_3MM'_2O_9$, that find application in microwave telecommunications.

Item Type:	Journal Article
Publication:	Journal of Marterials Chemistry
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	09 Jul 2007
Last Modified:	24 Jan 2012 10:03
URI:	http://eprints.iisc.ac.in/id/eprint/11452

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