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An ESR investigation of the electronic localization on nickel (III) in perovskite-type rare-earth-nickel oxides

Ganguly, P and Demazeau, G and Dance, JM and Hagenmuller, P (1990) An ESR investigation of the electronic localization on nickel (III) in perovskite-type rare-earth-nickel oxides. In: Solid State Communications, 73 (9). pp. 617-622.

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Official URL: http://dx.doi.org/10.1016/0038-1098(90)90250-F

Abstract

An ESR investigation has been carried out between 4 and 300K on $La_{1-y}Y_yAl_{1-x}Ni_xO_3$ perovskites giving evidence of low-spin $Ni(III)$ as expected from the behavior of $LaNiO_3$ and $YNiO_3$. Magnetic susceptibility measurements support those conclusions. It appears that substitution of $Y$ for $La$ increases the g-values and favors the static Jahn-Teller effect with respect to the dynamic one. The results are discussed assuming that $LaNiO_3$ is metallic and $YNiO_3$ an insulator.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Depositing User: Ramya Krishna
Date Deposited: 10 Jul 2007
Last Modified: 25 Jan 2012 05:21
URI: http://eprints.iisc.ac.in/id/eprint/11470

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