CeOx as Surface Passivation and Hole Transfer Catalyst Layer Boosting Solar Water Oxidation of ZnFe2O4 Nanorods Photoanode

Maity, D and Pal, D and Saha, S and Punetha, P and Sarkar, D and De, D and Khan, GG and Mandal, K (2022) CeOx as Surface Passivation and Hole Transfer Catalyst Layer Boosting Solar Water Oxidation of ZnFe2O4 Nanorods Photoanode. In: Advanced Materials Interfaces .

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Abstract

Severe surface photocarrier recombination and poor electronic conductivity are the major factors behind the sluggish photoelectrochemical water oxidation kinetics of the ZnFe2O4 photoanode. Here, the CeOx catalyst overlayer has been coupled with the reduced ZnFe2O4 nanorods (NRs) to reduce the surface charge recombination on the photoanode significantly. The density functional theory (DFT) studies indicate that the oxygen vacancy defect-rich CeOx catalyst constructs a favorable band alignment with ZnFe2O4 promoting rapid photocarrier separation and serves as a conducting photocarrier transfer pathway accelerating the hole transportation toward the electrode/electrolyte interface. The ZnFe2O4/CeOx nano-heterostructure photoanode exhibits a current density of 0.64 mA cm−2 at 1.23 V versus RHE under AM 1.5 G illumination, which corresponds to >167% increase over that of the ZnFe2O4 NRs photoanode. The CeOx coupling reduces the onset potential cathodically by 180 mV over the ZnFe2O4 NRs photoanode. The ZnFe2O4/CeOx nano-heterostructure photoanode also exhibits excellent charge transfer efficiency (≈64% at 1.23 V vs RHE) and photostability. The results indicate the superior catalytic performance of oxygen vacancy defect-rich CeOx in the PEC process. This work demonstrates the multifunctional role of CeOx as a surface passivation overlayer, hole transfer layer, and efficient oxygen evolution reaction catalyst.

Item Type:	Journal Article
Publication:	Advanced Materials Interfaces
Publisher:	John Wiley and Sons Inc
Additional Information:	The copyright for this article belongs to John Wiley and Sons Inc.
Keywords:	Catalysts; Cerium compounds; Charge transfer; Density functional theory; Iron compounds; Oxygen; Oxygen vacancies; Passivation; Photoelectrochemical cells; Zinc compounds, Co catalysts; Hole transfer; Nano-heterostructures; Overlayers; Oxygen evolution; Oxygen vacancy defects; Photo-anodes; Photo-carriers; Surface passivation; ]+ catalyst, Nanorods
Department/Centre:	Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited:	09 Jan 2023 07:19
Last Modified:	09 Jan 2023 07:19
URI:	https://eprints.iisc.ac.in/id/eprint/78916

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