Prasad, Kavirayani R and Anbarasan, Pazhamalai (2005) Asymmetric synthesis of unsaturated \alpha-benzyloxyaldehydes: an enantioselective synthesis of (+)-exo-brevicomin. [Journal Article]
![[thumbnail of av114.pdf]](http://eprints.iisc.ac.in/style/images/fileicons/application_pdf.png)
av114.pdf
Restricted to Registered users only
Download (94kB) | Request a copy
Abstract
Enantioselective synthesis of \alpha-hydroxy aldehydes with an alkene tether was accomplished front L-(+)-tartaric acid, employing stereoselective reduction of a 1,4-diketone with L-selectride as the key step. Synthetic utility of these aldehydes was demonstrated in the synthesis of pine beetle pheromone (+)-exo-brevicomin.
Item Type: | Journal Article |
---|---|
Additional Information: | Copyright for this article belongs to Elsevier. |
Subjects: | Division of Chemical Sciences > Organic Chemistry |
Depositing User: | B.S Priyanka |
Date Deposited: | 19 Jan 2006 |
Last Modified: | 19 Sep 2010 04:23 |
URI: | http://eprints.iisc.ac.in/id/eprint/5164 |