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Molecular Structures of Methyl 5,6-Diaryl-1,2,4-trimethyl-7-oxobicyclo[2.2.1]hept-5-en-2-endo-carboxylates (aryl = phenyl or o-methoxyphenyl)

Balasubrahmanyam, Natarajan S and Rao, Sunkada P and Bhadbhade, Mohan M and Sudarsanakumar, C and Joseph, Bubbly K (2000) Molecular Structures of Methyl 5,6-Diaryl-1,2,4-trimethyl-7-oxobicyclo[2.2.1]hept-5-en-2-endo-carboxylates (aryl = phenyl or o-methoxyphenyl). In: Bulletin of the Chemical Society of Japan, 73 (4). pp. 941-949.

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Abstract

Structural assignments based on a reconstruction from the $^1H$ NMR dynamic behavior of the three 5,6-bis(substituted aryl)-7-oxo-5-norbornene-2-carboxylic esters named in the title have received confirmation from X-ray crystallographic studies. The specific structural features of these systems are compared among themselves and with those of 7-oxo-5,6-diphenyl-5-norbornene-2-carboxylic esters, analogues systems without substitution on the phenyl groups, which were studied earlier.

Item Type: Journal Article
Publication: Bulletin of the Chemical Society of Japan
Publisher: The Chemical Society of Japan
Additional Information: Copyright of this article belongs to The Chemical Society of Japan.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 01 Aug 2008
Last Modified: 27 Aug 2008 13:40
URI: https://eprints.iisc.ac.in/id/eprint/15407

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