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ac conductivity and transport studies in phosphate glasses with NASICON-type chemistry

Sobha, KC and Rao, KJ (1995) ac conductivity and transport studies in phosphate glasses with NASICON-type chemistry. In: Solid State Ionics, 81 (1-2). pp. 145-156.

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Abstract

ac conductivity studies conducted on glasses with NASICON-type chemistry reveal many universalities in their behaviour. It is found that the total conductivity of all the glasses at all temperatures can be fitted well with a double power law using $s_1 = 0.5$ and $s_2 = 1.0$. It is found that the plots of reduced conductivity (with respect to the dc conductivity) versus reduced frequency (with respect to M peak frequency) are superimposable for all the glasses at all temperatures, indicating that the ionic conductivity in these materials is independent of a number of factors like the nature and concentration of the cation and structure of the glass.

Item Type: Journal Article
Publication: Solid State Ionics
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: Glass;Ionic conductivity - sodium;NASICON
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 22 Aug 2008
Last Modified: 19 Sep 2010 04:35
URI: http://eprints.iisc.ac.in/id/eprint/9824

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