Design and synthesis of a Pt(II) nanoscopic trigonal bipyramidal cage using a new tripodal ester-containing ligand

Ghosh, Sushobhan and Mukherjee, Partha Sarathi (2006) Design and synthesis of a Pt(II) nanoscopic trigonal bipyramidal cage using a new tripodal ester-containing ligand. In: Tetrahedron Letters, 47 (52). pp. 9297-9300.

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Abstract

The formation of a Pt(II) nanoscopic trigonal bipyramidal cage (TBP) containing a new tripodal linker with ester functionality is achieved by self-assembly. The new tripod ligand and the cage were characterized by multinuclear NMR and electrospray ionization mass spectroscopy. Energy minimized simulation of the cage yielded a pseudo TBP shape with an internal diameter of 2 nm.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier
Additional Information:	Copyright of this article belongs to Elsevier
Keywords:	Supramolecular assemblies;Tripod ligand;TBP cage;Electrospray ionization
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 Jan 2007
Last Modified:	19 Sep 2010 04:34
URI:	http://eprints.iisc.ac.in/id/eprint/9570

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