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Nematic mixture methods for the determination of chemical shift anisotropy

Khetrapal, CL and Suryaprakash, N and Vivekanandan, S (1998) Nematic mixture methods for the determination of chemical shift anisotropy. In: Chemical Physics Letters, 296 (5-6). pp. 537-540.

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The discrepancy in the $^1H$ and $^1^3C$ chemical shift anisotropy values for chloroform determined using ENEMIX and other [methods J. Vaara, K. Oikarinen, J. Jokisaari, J. Lounila, Chem. Phys. Lett. 253 (1996) 340] has been shown to arise from the use of the reference compound and not because of hydrogen bonding between chloroform and the cyanide group of the solvent used. The NEMIX method [C.L. Khetrapal, A.C. Kunwar, Chem. Phys. Lett. 82 (1981) 170] is shown to give more consistent results.

Item Type: Journal Article
Publication: Chemical Physics Letters
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Sophisticated Instruments Facility (Continued as NMR Research Centre)
Date Deposited: 18 Jan 2007
Last Modified: 19 Sep 2010 04:34
URI: http://eprints.iisc.ac.in/id/eprint/9533

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