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Off-Resonance Effects in Two-Dimensional NQR Spectroscopy Using a Single Crystal

Ajithkumar, TG and Ramanathan, KV and Mathias, PC and Kumar, Anil (1998) Off-Resonance Effects in Two-Dimensional NQR Spectroscopy Using a Single Crystal. In: Journal of Magnetic Resonance, 135 (1). pp. 165-168.

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Two-dimensional nutation pure NQR experiments on $^{35}Cl$ have been carried out on a single crystal of $NaClO_3$. The 22D nutation experiment separates out different orientations of each chemically equivalent site in a unit cell as a separate frequency in the $\omega _1$ domain. The squares of the observed frequencies lie on a straight line with respect to the squares of the offsets, confirming the expected offset dependence quantitatively. The intercepts at zero offset yield the relative orientations of the efg tensors with respect to the axis of the radiofrequency coil.

Item Type: Journal Article
Publication: Journal of Magnetic Resonance
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 11 Jan 2007
Last Modified: 19 Sep 2010 04:34
URI: http://eprints.iisc.ac.in/id/eprint/9459

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