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On the stability of lithium during ageing of $Li/PEO_8LiClO_4/Li cells$

Munichandraiah, N and Shukla, AK and Scanlon, LG and Marsh, RA (1996) On the stability of lithium during ageing of $Li/PEO_8LiClO_4/Li cells$. In: Journal of Power Sources, 62 (2). pp. 201-206.

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Symmetrical cells consisting of a thin film of $PEO_8LiClO_4$ solid-polymer electrolyte sandwiched between two lithium electrodes have been subjected to galvanostatic polarization and concomitant voltage changes measured at several intervals of ageing at ambient temperature. The interfacial resistance is found to increase gradually over about 150 days of ageing. The exponential increase of cell voltage is interpreted in the light of the diffusion-limited lithium-ion transport across the passive surface film on lithium.

Item Type: Journal Article
Publication: Journal of Power Sources
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: Lithium;Solid-polymer electrolytes;Passive films;Diffusion
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 17 Jan 2007
Last Modified: 19 Sep 2010 04:33
URI: http://eprints.iisc.ac.in/id/eprint/9327

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