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Ion solvation dynamics in supercritical water

Biswas, Ranjit and Bagchi, Biman (1998) Ion solvation dynamics in supercritical water. In: Chemical Physics Letters, 290 (1-3). pp. 223-228.

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A theoretical study of ionic solvation dynamics in supercritical water is presented. The short-time decay of the calculated equilibrium solvation energy time correlation function $(S_E(t))$ is found to be in good agreement with the recent computer E simulation results. The simulated long-time decay is, however, somewhat slower than that which is predicted by the present theory. Two plausible molecular explanations for the slow long-time decay of $(S_E(t))$ are offered.

Item Type: Journal Article
Publication: Chemical Physics Letters
Publisher: Elsevier
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 03 Jan 2007
Last Modified: 19 Sep 2010 04:33
URI: http://eprints.iisc.ac.in/id/eprint/9188

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