Mondal, RR and Pal, AK and Geetharani, K (2024) Catalyst-Free Diborylation and Silaboration of Azoarenes: A Simple Photoinduced Approach. In: Angewandte Chemie - International Edition .
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Official URL: https://doi.org/10.1002/anie.202415913
Abstract
The diborylation of the N=N double bond of azoarenes has been achieved using a commercially available diboron reagent, B2cat2 bis(catecholato)diboron. By utilizing the photo-switchable nature of azoarenes under blue-LED light irradiation, an uncatalyzed diborylation and silaboration yielded a broad range of functionalized hydrazine derivatives. The mechanistic origin validates the importance of cis configuration, which is corroborated by theoretical calculations. © 2024 Wiley-VCH GmbH.
| Item Type: | Journal Article |
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| Publication: | Angewandte Chemie - International Edition |
| Publisher: | John Wiley and Sons Inc |
| Additional Information: | The copyright for this article belongs to authors. |
| Keywords: | Azoarenes; Blue LEDs; Catalyst-free; Diboron reagent; Diborylation; Double bonds; Photo-induced; Photo-switchable; Silaboration; Simple++ |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 27 Nov 2024 10:59 |
| Last Modified: | 27 Nov 2024 10:59 |
| URI: | http://eprints.iisc.ac.in/id/eprint/86992 |
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