Changing optical properties of black carbon and brown carbon aerosols during long-range transport from the Indo-Gangetic Plain to the equatorial Indian Ocean

Budhavant, K and Manoj, MR and Nair, HRCR and Gaita, SM and Holmstrand, H and Salam, A and Muslim, A and Satheesh, SK and Gustafsson, � (2024) Changing optical properties of black carbon and brown carbon aerosols during long-range transport from the Indo-Gangetic Plain to the equatorial Indian Ocean. In: Atmospheric Chemistry and Physics, 24 (20). pp. 11911-11925.

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Abstract

Atmospheric aerosols strongly influence the global climate through their light absorption properties (e.g., black carbon (BC) and brown carbon (BrC)) and scattering properties (e.g., sulfate). This study presents simultaneous measurements of ambient-aerosol light absorption properties and chemical composition obtained at three large-footprint southern Asian receptor sites during the South Asian Pollution Experiment (SAPOEX) from December 2017 to March 2018. The BC mass absorption cross section (BC-MAC678) values increased from 3.5 ± 1.3 at the Bangladesh Climate Observatory at Bhola (BCOB), located at the exit outflow of the Indo-Gangetic Plain, to 6.4 ± 1.3 at two regional receptor observatories, the Maldives Climate Observatory at Hanimaadhoo (MCOH) and the Maldives Climate Observatory at Gan (MCOG), representing an increase of 80 . This likely reflects a scavenging fractionation, resulting in a population of finer BC with higher MAC678 that has greater longevity. At the same time, BrC-MAC365 decreased by a factor of 3 from the Indo-Gangetic Plain (IGP) exit to the equatorial Indian Ocean, likely due to photochemical bleaching of organic chromophores. The high chlorine-to-sodium ratio at the BCOB, located near the source region, suggests a significant contribution of chorine from anthropogenic activities. Particulate Cl� has the potential to be converted into Cl radicals, which can affect the oxidation capacity of polluted air. Moreover, Cl� is shown to be nearly fully consumed during long-range transport. The results of this synoptic study, conducted on a large southern Asian scale, provide rare observational constraints on the optical properties of ambient BC (and BrC) aerosols over regional scales, away from emission sources. They also contribute significantly to understanding the aging effect of the optical and chemical properties of aerosols as pollution from the Indo-Gangetic Plain disperses over the tropical ocean. © Author(s) 2024.

Item Type:	Journal Article
Publication:	Atmospheric Chemistry and Physics
Publisher:	Copernicus Publications
Additional Information:	The copyright for this article belongs to the publishers.
Keywords:	aerosol; black carbon; brown carbon; chemical composition; long range transport; optical property; particulate matter, Gangetic Plain; Indian Ocean; Indian Ocean (Equatorial)
Department/Centre:	Division of Mechanical Sciences > Divecha Centre for Climate Change
Date Deposited:	04 Dec 2024 17:17
Last Modified:	04 Dec 2024 17:17
URI:	http://eprints.iisc.ac.in/id/eprint/86896

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