Diastereoselective Addition of Lithiated Allenyl Sulfones to Nonracemic Sulfinimines: Asymmetric Synthesis of Diverse Heterocycles

Gadhave, MS and Prasad, KR (2024) Diastereoselective Addition of Lithiated Allenyl Sulfones to Nonracemic Sulfinimines: Asymmetric Synthesis of Diverse Heterocycles. In: Journal of Organic Chemistry, 89 (20). 15364 -15373.

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Abstract

The addition of lithiated allenyl sulfones to nonracemic sulfinimines furnished sulfinamides possessing the allenyl sulfonyl moiety with excellent diastereoselectivity. The formed products are transformed into different heterocycles, including the synthesis of pyrroline, pyran, and functionalized benzopyran. © 2024 American Chemical Society.

Item Type:	Journal Article
Publication:	Journal of Organic Chemistry
Publisher:	American Chemical Society
Additional Information:	The copyright for this article belongs to the publisher.
Keywords:	Allenyl; Asymmetric synthesis; Benzopyrans; Diastereoselective additions; Diastereoselectivities; Functionalized; Heterocycles; Pyrrolines; Sulfinamides; Sulfinimines
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	24 Oct 2024 11:29
Last Modified:	24 Oct 2024 11:29
URI:	http://eprints.iisc.ac.in/id/eprint/86610

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