Photocatalytic C-H activation for C-N/C-S bond formation over highly efficient solar light active supramolecular network organogels

Srivastava, G and Yadav, RK and Shahin, R and Mishra, S and Yadav, AN and Yadav, SS and Kumari, I and Singh, K and Baeg, JO and Gupta, NK (2024) Photocatalytic C-H activation for C-N/C-S bond formation over highly efficient solar light active supramolecular network organogels. In: Journal of Sol-Gel Science and Technology, 111 (1). pp. 144-155.

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Abstract

Although using solar energy for pharmaceutical manufacture presents hurdles, the potential benefits in terms of sustainability, cost-effectiveness, and technical innovation make it an exciting path for the scientific community to investigate and develop further. We present a highly efficient solar light active supramolecular network organogels as a photocatalyst. The as-prepared PVA@RhB and PVA@RhB@OG organogels as a photocatalyst catalytic materials were used to create C-N and C-S bonds for drug intermediates and value-added products because of their high bond energy, low polarity, and strong inertia C-H bond activation. The current research work sets a new standard for the environmentally friendly, highly selective C-H activation for the production of C-N/C-S bonds under solar light. Graphical Abstract: (Figure presented.) © The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024.

Item Type:	Journal Article
Publication:	Journal of Sol-Gel Science and Technology
Publisher:	Springer
Additional Information:	The copyright for this article belongs to Springer.
Keywords:	Chemical bonds; Cost effectiveness; Rhodium compounds; Solar energy; Solar light, Aerobic oxidative cyclization; Bond formation; Organogels; Oxidative cyclization; Photo-catalytic; PVA@RhB organogel photocatalyst; PVA@RhB@OG organogel photocatalyst; Solar light; Supramolecular networks, Chemical activation
Department/Centre:	Division of Mechanical Sciences > Centre for Sustainable Technologies (formerly ASTRA)
Date Deposited:	19 Aug 2024 11:54
Last Modified:	19 Aug 2024 11:54
URI:	http://eprints.iisc.ac.in/id/eprint/85476

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