Solar-powered CO2 marvel: ultrahigh graphene quantum dots covalently coupled with PhS unleash effective photocatalysis for valuable chemical transformation

Agrawal, J and Shahin, R and Singh, C and Singh, S and Shukla, RK and Mishra, S and Singh, P and Baeg, J-O and Yadav, RK and Gupta, NK (2023) Solar-powered CO2 marvel: ultrahigh graphene quantum dots covalently coupled with PhS unleash effective photocatalysis for valuable chemical transformation. In: 2023 11th National Power Electronics Conference, NPEC 2023, 12.12.2023 to 16.12.2023, Guwahati.

PDF 2023_11th_nat_pow_ele_cor_npce_2023.pdf - Published Version Restricted to Registered users only Download (1MB)

Abstract

Carbon dioxide is particularly significant because it is the most prevalent greenhouse gas emitted by human activities. It is released when fossil fuels such as coal, oil, and natural gas are burned for energy production, transportation, and industrial processes. Many strategies are being pursued to address this stumbling block and ensure that the tremendously growing demand for global energy can be satisfied in a justifiable manner. On a large scale, technologies have been developed for the hydrogenation of CO2 into alcohols and acids, but their industrial applications are limited due to the high price of renewable hydrogen and pure CO2 availability. Particular attention is being paid to this field due to the increased levels of CO2 in the atmosphere, leading to a rise in global temperatures. Therefore, converting CO2 into important value-added solar chemicals through CO2 fixation has been a challenging task for the scientific community. Herein, we account for the solar-powered CO2 marvel: ultrahigh graphene quantum dots covalently coupled with PhS unleash effective photocatalysis for valuable chemical transformation. The coupled GQDCCPhS photoreactor plays a photocatalyst role in an extremely selective and proficient manner, leading to more coenzyme (1,4-NADH) photo-regeneration (61.09), pursued by its consumption in exclusive value-added chemical (formic acid) production (163.04 μmol) by utilizing CO2. The current study effort emphasizes that developing a GQDCCPhS photoreactor to capture CO2 emissions from power plants and industrial facilities can help prevent them from entering the atmosphere and also result in the perfect example for selective production of formic acid, i.e., solar chemicals via solar radiation. © 2024 RSC.

Item Type:	Conference Proceedings
Publication:	RSC Sustainability
Publisher:	Royal Society of Chemistry
Additional Information:	The copyright for this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Mechanical Sciences > Centre for Sustainable Technologies (formerly ASTRA)
Date Deposited:	04 Mar 2024 07:16
Last Modified:	04 Mar 2024 07:16
URI:	https://eprints.iisc.ac.in/id/eprint/84231

Actions (login required)

View Item