Allylic Activation by Copper(I): Reactivity Comparable with Catalysis by Palladium

Baruah, Jubaraj B and Samuelson, Ashoka G (1987) Allylic Activation by Copper(I): Reactivity Comparable with Catalysis by Palladium. In: Journal of the Chemical Society, Chemical Communications . pp. 36-37.

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Abstract

Allylic chlorides and acetates accelerate the reaction between copper(II) perchlorate and copper metal powder to form copper(I) perchlorate which in turn is an extremely good catalyst for the activation of these substrates towards nucleophilic substitution.

Item Type:	Journal Article
Publication:	Journal of the Chemical Society, Chemical Communications
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	16 Aug 2006
Last Modified:	19 Sep 2010 04:31
URI:	http://eprints.iisc.ac.in/id/eprint/8278

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