Sahoo, D and Shakya, J and Choudhury, S and Roy, SS and Devi, L and Singh, B and Ghosh, S and Kaviraj, B (2021) High-Performance MnO2Nanowire/MoS2Nanosheet Composite for a Symmetrical Solid-State Supercapacitor. In: ACS Omega .
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Abstract
To improve the production rate of MoS2 nanosheets as an excellent supercapacitor (SC) material and enhance the performance of the MoS2-based solid-state SC, a liquid phase exfoliation method is used to prepare MoS2 nanosheets on a large scale. Then, the MnO2 nanowire sample is synthesized by a one-step hydrothermal method to make a composite with the as-synthesized MoS2 nanosheets to achieve a better performance of the solid-state SC. The interaction between the MoS2 nanosheets and MnO2 nanowires produces a synergistic effect, resulting in a decent energy storage performance. For practical applications, all-solid-state SC devices are fabricated with different molar ratios of MoS2 nanosheets and MnO2 nanowires. From the experimental results, it can be seen that the synthesized nanocomposite with a 1:4 M ratio of MoS2 nanosheets and MnO2 nanowires exhibits a high Brunauer-Emmett-Teller surface area (118 m2/g), optimum pore size distribution, a specific capacitance value of 212 F/g at 0.8 A/g, an energy density of 29.5 W h/kg, and a power density of 1316 W/kg. Besides, cyclic charging-discharging and retention tests manifest significant cycling stability with 84.1 capacitive retention after completing 5000 rapid charge-discharge cycles. It is believed that this unique, symmetric, lightweight, solid-state SC device may help accomplish a scalable approach toward powering forthcoming portable energy storage applications.
| Item Type: | Journal Article |
|---|---|
| Publication: | ACS Omega |
| Publisher: | American Chemical Society |
| Additional Information: | The copyright for this article belongs to the Authors. |
| Department/Centre: | Division of Physical & Mathematical Sciences > Physics |
| Date Deposited: | 22 May 2023 09:19 |
| Last Modified: | 22 May 2023 09:19 |
| URI: | https://eprints.iisc.ac.in/id/eprint/81713 |
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