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Cross Correlations in the Longitudinal Relaxation of Strongly Coupled Spins

Dorai, Kavita and Kumar, Anil (2000) Cross Correlations in the Longitudinal Relaxation of Strongly Coupled Spins. In: Journal of Magnetic Resonance, 145 (1). pp. 8-17.

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A generalized set of magnetization modes for quantifying crosscorrelation contributions to longitudinal relaxation in strongly coupled spin systems is described in this paper. Such a set of modes (called longitudinal multiple-quantum modes) is used to unravel cross-correlation information in strongly coupled systems, where the strength of the J coupling tends to obscure such effects.The applicability of such methods is demonstrated for a small molecule which exhibits some strong coupling effects even at high magnetic field strengths. The contribution of remote cross correlations to the longitudinal relaxation of strongly coupled spins is detailed.

Item Type: Journal Article
Publication: Journal of Magnetic Resonance
Publisher: Academic Press
Additional Information: Copyright of this article belongs to Academic Press.
Keywords: strong coupling;Cross correlations;Single-transition operators;Longitudinal multiple-quantum modes;Remote cross correlations
Department/Centre: Division of Chemical Sciences > Sophisticated Instruments Facility (Continued as NMR Research Centre)
Division of Physical & Mathematical Sciences > Physics
Date Deposited: 25 Aug 2008
Last Modified: 19 Sep 2010 04:30
URI: http://eprints.iisc.ac.in/id/eprint/8013

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