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Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene

Koneru, B and Swapnalin, J and Natarajan, S and Franco Jr, A and Banerjee, P (2022) Intercalation of Nanoscale Multiferroic Spacers between the Two-Dimensional Interlayers of MXene. In: ACS Omega, 7 (23). pp. 20369-20375.

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Official URL: https://doi.org/10.1021/acsomega.2c02471

Abstract

We report a facile synthesis of MXene/bismuth ferrite (Ti3C2Tx@ BiFeO3) nanocomposites using hydrazine hydrate induced with the hydrothermal method. Preparation of the composite with hydrazine hydrate prevents the formation of Bi25FeO39inside the matrix. The 25 wt loading of BiFeO3acts as spacers for the multilayer restacking of MXene flakes by retaining the (002) plane. This promotes large dc conductivity with interfacial and defect dipole polarization mechanisms inside the composite material. The thinner M-H loop also indicates the minimal magnetic loss inside the composites. The facile synthesis strategy provides outstanding properties in Ti3C2Tx@ BiFeO3composites as two-dimensional multiferroic materials.

Item Type: Journal Article
Publication: ACS Omega
Publisher: American Chemical Society
Additional Information: The copyright for this article belongs to the Author(s).
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 21 Sep 2022 09:01
Last Modified: 21 Sep 2022 09:01
URI: https://eprints.iisc.ac.in/id/eprint/76621

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