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Photobleaching dynamics in small molecule: Vs. polymer organic photovoltaic blends with 1,7-bis-trifluoromethylfullerene

Garner, LE and Nellissery Viswanathan, V and Arias, DH and Brook, CP and Christensen, ST and Ferguson, AJ and Kopidakis, N and Larson, BW and Owczarczyk, ZR and Pfeilsticker, JR and Ramamurthy, PC and Strauss, SH and Boltalina, OV and Braunecker, WA (2018) Photobleaching dynamics in small molecule: Vs. polymer organic photovoltaic blends with 1,7-bis-trifluoromethylfullerene. In: Journal of Materials Chemistry A, 6 (11). pp. 4623-4628.

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Official URL: https://doi.org/10.1039/C7TA10995D


Two organic photovoltaic (OPV) donor materials (one polymer and one small molecule) are synthesized from the same constituent building blocks, namely thiophene units, cyclopentathiophene dione (CTD), and cyclopentadithiophene (CPDT). Photobleaching dynamics of these donor materials are then studied under white light illumination in air with blends of PC70BM and the bis-trifluoromethylfullerene 1,7-C60(CF3)2. For both the polymer and small molecule blends, C60(CF3)2 stabilizes the initial rate of photobleaching by a factor of 15 relative to PC70BM. However, once the small molecule:C60(CF3)2 blend bleaches to ∼80% of its initial optical density, the rate of photobleaching dramatically accelerates, which is not observed in the analogous polymer blend. We probe that phenomenon using time-resolved photoluminescence (TRPL) to measure PL quenching efficiencies at defined intervals during the photobleaching experiments. The data indicates the small molecule donor and C60(CF3)2 acceptor significantly de-mix with time, after which the blend begins to bleach at approximately the same rate as the neat donor sample. The work suggests that perfluoroalkylfullerenes have great potential to stabilize certain OPV active layers toward photodegradation, provided their morphology is stable.

Item Type: Journal Article
Publication: Journal of Materials Chemistry A
Publisher: Royal Society of Chemistry
Additional Information: The copyright for this article belongs to the Authors.
Keywords: Bleaching; Cleaning; Molecules; Photobleaching; Synthesis (chemical), Building blockes; Donor materials; Organic photovoltaic (OPV); Organic photovoltaics; Perfluoroalkylfullerenes; Small molecules; Time-resolved photoluminescence; White-light illumination, Polymer blends
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 03 Sep 2022 03:47
Last Modified: 03 Sep 2022 03:47
URI: https://eprints.iisc.ac.in/id/eprint/76377

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