Electronic and Thermoelectric Properties of Transition Metal Substituted Tetrahedrites

Tippireddy, S and Chetty, R and Naik, MH and Jain, M and Chattopadhyay, K and Mallik, RC (2018) Electronic and Thermoelectric Properties of Transition Metal Substituted Tetrahedrites. In: Journal of Physical Chemistry C, 122 (16). pp. 8735-8749.

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Abstract

Abstract A detailed theoretical and experimental study is carried out to understand the effect of transition metal atom (TM) substitution at the Cu tetrahedral site in synthetic tetrahedrite material Cu12-xTMxSb4S13 (TM = Mn, Fe, Co, Ni, and Zn). The samples are prepared by solid state synthesis method with the desired compositions. The X-ray diffraction (XRD) pattern of all the samples reveal tetrahedrite as the main phase with traces of secondary phases, confirmed by Electron Probe Micro Analysis (EPMA). X-ray Photoelectron Spectroscopy (XPS) reveals that TM is in +2 oxidation state for all samples except for Fe which shows a + 3 oxidation state. Ultraviolet Photoelectron Spectroscopy (UPS) measurements show the highest work function for Cu11.5Co0.5Sb4S13, indicating high band degeneracy. Density Functional Theory (DFT) calculations reveal that TM substitution introduces spin polarized states within the band structure, thus, changing the band degeneracy and density of states (DOS) at the Fermi level (EF). It is confirmed from DFT calculations that band degeneracy is highest for Cu11.5Co0.5Sb4S13 among the TM substituted samples, with high DOS at EF, which is experimentally confirmed by magnetic susceptibility analysis. The electrical resistivity (ρ) and Seebeck coefficients (S) of the substituted samples are higher than the pristine compound due to compensation of holes caused by substitution of TM+2 or TM+3 on the Cu tetrahedral site. Because of the high band degeneracy and DOS at EF, a high power factor is achieved for the composition Cu11.5Co0.5Sb4S13, enabling it to attain the maximum figure of merit (zT) among the substituted tetrahedrite compositions. The paper presents a comprehensive study to understand the role of magnetic impurities (TM) in influencing the band structure and, hence, the transport properties in substituted tetrahedrite.

Item Type:	Journal Article
Publication:	Journal of Physical Chemistry C
Publisher:	American Chemical Society
Additional Information:	The copyright for this article belongs to the American Chemical Society.
Keywords:	Antimony compounds; Band structure; Copper; Copper compounds; Impurities; Magnetic susceptibility; Photoelectrons; Photons; Ultraviolet photoelectron spectroscopy; Uninterruptible power systems; X ray diffraction; X ray photoelectron spectroscopy, Density of state; High power factor; Magnetic impurity; Solid state synthesis method; Spin polarized state; Tetrahedral sites; Thermoelectric properties; Transition metal atoms, Density functional theory
Department/Centre:	Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy) Division of Physical & Mathematical Sciences > Physics
Date Deposited:	08 Aug 2022 06:35
Last Modified:	08 Aug 2022 06:35
URI:	https://eprints.iisc.ac.in/id/eprint/75574

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