Selective Reduction of Aromatic Nitro Compounds to Amines From Pd Doped TiO2 Catalyzed Nano Catalyst

Obaiah, GO and Bhat, SK and Shivaprasad, KH and Mylarappa, M (2022) Selective Reduction of Aromatic Nitro Compounds to Amines From Pd Doped TiO2 Catalyzed Nano Catalyst. In: 1st International Conference on Technologies for Smart Green Connected Society 2021, ICTSGS 2021, 29 November 2021 through 30 November 2021, Virtual, Online, pp. 1681-1687.

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Abstract

An efficient chemoselective reduction of aromatic nitro compounds to corresponding amino analogs was achieved using palladium doped TiO2 (Ti0.97Pd0.03O1.97) nanoparticles. The reductions are effectively carried out in the presence of aromatic nitro compounds of various other reducible functional groups such as halo, alkoxy, carbonyl, and cyanide. The reduction of aromatic nitro compounds to aromatic amines was recognized with excellent yield (100) by using Nanoporous palladium as a sustainable catalyst and as a hydrogen source. Reduced amines were well characterized using PXRD, 1H NMR, and 13C NMR, spectroscopy.

Item Type:	Conference Paper
Publication:	ECS Transactions
Publisher:	Institute of Physics
Additional Information:	The copyright for this article belongs to The Electrochemical Society,Institute of Physics
Department/Centre:	Centres under the Director > Talent Development Centre
Date Deposited:	13 Jul 2022 11:51
Last Modified:	13 Jul 2022 11:51
URI:	https://eprints.iisc.ac.in/id/eprint/74168

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