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Crystal and Magnetic Structures of Monoclinic FeOHSO4

Avdeev, M and Singh, S and Barpanda, P and Ling, CD (2021) Crystal and Magnetic Structures of Monoclinic FeOHSO4. In: Inorganic Chemistry, 60 (20). pp. 15128-15130.

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Official URL: https://doi.org/10.1021/acs.inorgchem.1c02544


The crystal and magnetic structures and properties of the monoclinic form of the iron hydroxysulfate FeOHSO4 were investigated by magnetometry and neutron powder diffraction. The space group C2/c was confirmed, and the proton position was located close to that predicted by ab initio calculations. The collinear antiferromagnetic k(0,0,0) structure forming below the Néel temperature TN �125 K is described by the C2�/c� (No. 15.89) magnetic space group, with the moments along the b axis. Overall, FeOHSO4 is isostructural to FeSO4F in terms of both the crystal and magnetic structures. © 2021 American Chemical Society.

Item Type: Journal Article
Publication: Inorganic Chemistry
Publisher: American Chemical Society
Additional Information: The copyright for this article belongs to American Chemical Society
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 26 Nov 2021 10:51
Last Modified: 26 Nov 2021 10:51
URI: http://eprints.iisc.ac.in/id/eprint/70464

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