Anil, AG and Sunil Kumar Naik, TS and Subramanian, S and Ramamurthy, PC (2021) A novel non-enzymatic urea sensor based on the nickel complex of a benzimidazoyl pyridine derivative. In: Journal of Electroanalytical Chemistry, 883 .
PDF
jou_ele_che_883_2021.pdf - Published Version Restricted to Registered users only Download (2MB) | Request a copy |
|
Microsoft Word
1-s2.0-S1572665721000886-mmc1.docx - Published Supplemental Material Restricted to Registered users only Download (5MB) | Request a copy |
Abstract
A nickel based organometallic complex is reported herein for non-enzymatic detection of urea. Nickel complex of benzimidazoyl pyridine (Ni(bzimpy)2Cl2) derivative offers an excellent nickel core for urea sensing. Cyclic voltammetry (CV) and linear sweep voltammetry (LSV) have been utilized for analysing the sensing behaviour of urea. The modified carbon paste electrode (MCPE) has a lower limit of detection (LOD) of 1.5 µM with a linear sensing range from 0.01 to 0.1 mm the sensor also exhibits prominent response towards urea, compared to other interferents. The substantial stability and reproducibility of the sensor is augmented by its high recovery rate in real world samples. The utility of the complex as a chemiresistor sensor has also been investigated. © 2021 Elsevier B.V.
Item Type: | Journal Article |
---|---|
Publication: | Journal of Electroanalytical Chemistry |
Publisher: | Elsevier B.V. |
Additional Information: | The copyright of this article belongs to Elsevier B.V. |
Department/Centre: | Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy) |
Date Deposited: | 09 Mar 2021 07:06 |
Last Modified: | 09 Mar 2021 07:06 |
URI: | http://eprints.iisc.ac.in/id/eprint/68189 |
Actions (login required)
View Item |