Iron-based catalyst for borylation of unactivated alkyl halides without using highly basic organometallic reagents

Siddiqui, S and Bhawar, R and Geetharani, K (2021) Iron-based catalyst for borylation of unactivated alkyl halides without using highly basic organometallic reagents. In: Journal of Organic Chemistry, 86 . pp. 1948-1954.

	PDF Ironbased-catalyst-for-borylation-of-unactivated-alkyl-halides-without-using-highly-basic-organometallic-reagents2021Journal-of-Organic-Chemistry.pdf - Published Version Restricted to Registered users only Download (1MB) | Request a copy
	PDF jo0c02364_si_001.pdf - Published Supplemental Material Restricted to Registered users only Download (3MB) | Request a copy

Abstract

The mild borylation of alkyl bromides and chlorides with bis(neopentylglycolato)diborane (B2neop2) mediated by iron-bis amide is described. The reaction proceeds with a broad substrate scope and good functional group compatibility. Moreover, sufficient catalytic activity was obtained for primary and secondary alkyl halides. Mechanistic studies indicate that the reaction proceeds through a radical pathway. © XXXX American Chemical Society.

Item Type:	Journal Article
Publication:	Journal of Organic Chemistry
Publisher:	American Chemical Society
Additional Information:	Copyright to this article belongs to American Chemical Society
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	28 Jan 2021 06:32
Last Modified:	28 Jan 2021 06:32
URI:	http://eprints.iisc.ac.in/id/eprint/67816

Actions (login required)

View Item