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Development of a new arylamination reaction catalyzed by polymer bound 1,3-(Bisbenzimidazolyl) benzene co(ii) complex and generation of bioactive adamanate amines

Pookunoth, BC and Rao, SE and Deveshegowda, SN and Metri, PK and Fazl-Ur-rahman, K and Periyasamy, G and Virupaiah, G and Priya, BS and Pandey, VK and Lobie, PE and Subbegowda, RK and Basappa, Basappa (2020) Development of a new arylamination reaction catalyzed by polymer bound 1,3-(Bisbenzimidazolyl) benzene co(ii) complex and generation of bioactive adamanate amines. In: Catalysts, 10 (11). pp. 1-15.

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Official URL: https://doi.org/10.3390/catal10111315

Abstract

We herein report the preparation and characterization of an inexpensive polymer supported 1,3-bis(benzimidazolyl)benzeneCo(II) complex PS-Co(BBZN)Cl2 as a catalyst by using the polymer (divinylbenzene cross-linked chloromethylated polystyrene), on which 1,3-bis(benzimidazolyl) benzeneCo(II) complex (PS-Co(BBZN)Cl2 ) has been immobilized. This�catalyst was employed to develop arylamination reaction and robustness of the same reaction was demonstrated by synthesizing various bioactive adamantanyl-tethered-biphenylamines. Our synthetic methodology was much improved than reported methods due to the use of an inexpensive and recyclable catalyst. © MDPI AG. All rights reserved.

Item Type: Journal Article
Publication: Catalysts
Publisher: MDPI AG
Additional Information: The copyright of this article belongs to Authors
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 28 Jul 2021 10:15
Last Modified: 28 Jul 2021 10:15
URI: http://eprints.iisc.ac.in/id/eprint/67326

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