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An efficient ring-closing metathesis reaction of geminally disubstituted olefins using first generation Grubbs’ catalyst: enantiospecific synthesis of pacifigorgianes

Srikrishna, A and Dethe, Dattatraya H (2003) An efficient ring-closing metathesis reaction of geminally disubstituted olefins using first generation Grubbs’ catalyst: enantiospecific synthesis of pacifigorgianes. In: Tetrahedron Letters, 44 (42). pp. 7817-7820.

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Abstract

An efficient ring closing metathesis reaction with first generation Grubbs’ catalyst $[PhCH=RuCl_2(PCy_3)_2]$ involving geminally disubstituted olefins has been discovered. It has been extended to the enantiospecific synthesis of pacifigorgiane sesquiterpenes.

Item Type: Journal Article
Publication: Tetrahedron Letters
Publisher: Elsevier
Additional Information: The Copyright belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 17 May 2006
Last Modified: 19 Sep 2010 04:26
URI: http://eprints.iisc.ac.in/id/eprint/6714

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