An efficient ring-closing metathesis reaction of geminally disubstituted olefins using first generation Grubbs’ catalyst: enantiospecific synthesis of pacifigorgianes

Srikrishna, A and Dethe, Dattatraya H (2003) An efficient ring-closing metathesis reaction of geminally disubstituted olefins using first generation Grubbs’ catalyst: enantiospecific synthesis of pacifigorgianes. In: Tetrahedron Letters, 44 (42). pp. 7817-7820.

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Abstract

An efficient ring closing metathesis reaction with first generation Grubbs’ catalyst $[PhCH=RuCl_2(PCy_3)_2]$ involving geminally disubstituted olefins has been discovered. It has been extended to the enantiospecific synthesis of pacifigorgiane sesquiterpenes.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier
Additional Information:	The Copyright belongs to Elsevier.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	17 May 2006
Last Modified:	19 Sep 2010 04:26
URI:	http://eprints.iisc.ac.in/id/eprint/6714

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