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Chapter 19: Long-lived Spin Order Coupled to SABRE

Roy, SS (2020) Chapter 19: Long-lived Spin Order Coupled to SABRE. [Book Chapter]

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Official URL: https://dx.doi.org/10.1039/9781788019972-00350


This chapter reports on the recent developments in the field of the Signal Amplification by Reversible Exchange (SABRE) nuclear spin hyperpolarisation technique in conjunction with the long-lived states (LLS) associated with nuclear spins. The underlying feature of the para-hydrogen driven SABRE technique is discussed in relation to nuclear singlet states. Examples of substrates containing 1H, 13C, and 15N spin-pairs are presented to highlight the exciting feature of hyperpolarised long-lived states (Hyper-LLS) spin order with lifetimes in the order of tens of minutes. Furthermore, the theoretical calculations and resonance conditions in achieving such Hyper-LLS have also been discussed. Finally, this account highlights the challenges and criticalities in the field whilst discussing its future directions. © The Royal Society of Chemistry 2020.

Item Type: Book Chapter
Publication: New Developments in NMR
Series.: New Developments in NMR
Publisher: Royal Society of Chemistry
Additional Information: The copyright of this article belongs to Royal Society of Chemistry
Keywords: Cytology; Spin dynamics, Hyperpolarised; Long-lived state; Nuclear spins; Para-hydrogen; Resonance condition; Signal amplifications; Singlet state; Theoretical calculations, Nuclear magnetic resonance spectroscopy, calculation; hyperpolarization
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 08 Oct 2020 09:32
Last Modified: 08 Oct 2020 09:32
URI: http://eprints.iisc.ac.in/id/eprint/66497

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