Coriolis Interactions in benzene-water and related molecular complexes

Halder, P and Krishnan, MS and Arunan, E (2020) Coriolis Interactions in benzene-water and related molecular complexes. In: Journal of Molecular Spectroscopy, 370 .

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Abstract

Rotational spectra of benzene-water and several related complexes were fit according to a free internal rotor model over the last three decades, though the model did not explain all of the excited state transitions found or yield an RMS deviation within experimental uncertainty. We use a model Hamiltonian, including Coriolis interactions that is able to explain all excited state transitions observed, giving a fit with an RMS deviation within experimental uncertainty. © 2020 Elsevier Inc.

Item Type:	Journal Article
Publication:	Journal of Molecular Spectroscopy
Publisher:	Academic Press Inc.
Additional Information:	Copyright for this article belongs to Academic Press Inc
Keywords:	Benzene, Coriolis interaction; Experimental uncertainty; Internal-rotor; Model Hamiltonians; Molecular complexes; Rms deviations; Rotational spectra; State transitions, Excited states
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	11 Sep 2020 09:41
Last Modified:	11 Sep 2020 09:41
URI:	http://eprints.iisc.ac.in/id/eprint/65289

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