Das, A and Jayaraman, N (2020) Aspects of chemical transglycosylations in modern glycoside synthesis. In: Journal of the Indian Chemical Society, 97 (2). pp. 135-156.
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Abstract
Application of chemical methods forms as a powerful approach to achieve synthesis of custom-designed oligosaccharides. Chemical glycosylation methods continue to evolve till date even when the first such method dates back more than a century ago. The recent past has witnessed the emergence of the transglycosylations, wherein a preponderant O-glycoside acts as a glycosyl donor to afford yet another O-glycoside product bearing the newly introduced glycan/aglycan at the reducing end. Critical requirements of the aglycan portion of a glycoside donor are discussed, as also the mechanistic formulations based on a set of experimental observations. A critical review of the expanding facets of transglycosylations in the garb of modern glycosylation methods is presented herein. © 2020 Scientific Publishers. All rights reserved.
Item Type: | Journal Article |
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Publication: | Journal of the Indian Chemical Society |
Publisher: | Scientific Publishers |
Additional Information: | The Copyright of this article belongs to Scientific Publishers |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 23 Aug 2021 09:06 |
Last Modified: | 23 Aug 2021 09:06 |
URI: | http://eprints.iisc.ac.in/id/eprint/64971 |
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