Gaykar, Rahul N and Guin, Avishek and Bhattacharjee, Subrata and Biju, Akkattu T (2019) Three-Component Aminoselenation of Arynes. In: ORGANIC LETTERS, 21 (23). pp. 9613-9617.
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Official URL: https:/dx.doi.org/10.1021/acs.orglett.9b03789
Abstract
The three-component coupling of tertiary amines, arynes, and aryl selenium bromide or diaryl diselenide as an electrophilic selenium source allowing the synthesis of 2-selanyl aniline derivatives is reported. This aminoselenation reaction of arynes installs a C-N and C-Se bond under mild conditions, and the products are formed in moderate to good yields. This reaction is compatible with various functional groups, and the preliminary studies on the mechanism of the reaction is also provided.
| Item Type: | Journal Article |
|---|---|
| Publication: | ORGANIC LETTERS |
| Publisher: | AMER CHEMICAL SOC |
| Additional Information: | Copyright of this article belongs to AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Keywords: | TRANSITION-METAL-FREE; COUPLING INVOLVING ARYNES; EMPLOYING ARYNES; STRAIGHTFORWARD ACCESS; ANTIOXIDANT PROPERTIES; ISOCYANIDES; CHEMISTRY; ORGANOSELENIUM; HETEROCYCLES; ANALOGS |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 06 Jan 2020 08:51 |
| Last Modified: | 06 Jan 2020 08:51 |
| URI: | http://eprints.iisc.ac.in/id/eprint/64293 |
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