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Hexaaquanickel(II) dichromate bis(hexa-methylenetetramine) monohydrate

Dagur, Pritesh and Chopra, Deepak and Prakash, AS and Row, Guru TN and Hegde, MS (2003) Hexaaquanickel(II) dichromate bis(hexa-methylenetetramine) monohydrate. In: Acta Crystallographica Section E: Structure Reports Online, 59 (12). m1129-m1130.

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A novel compound consisting of a hydrated metal cation, an organic molecule, an inorganic complex anion and water of crystallization has been synthesized and is found to crystallize in the monoclinic space group $P2_1/c$. The structure of the title compound, $[Ni(H_2O)_6][Cr_2O_7]\cdot 2 C_6H_{12}N4 \cdot H_2O$, contains octahedrally coordinated nickel ions and discrete dichromate anions. The hexamethylenetetramine molecules have no direct coordination to the metal ions. There are two cations, two anions, four tetramine molecules and two uncoordinated water molecules in the asymmetric unit. The structure is stabilized by extensive intra- and intermolecular hydrogen bonding.

Item Type: Journal Article
Publication: Acta Crystallographica Section E: Structure Reports Online
Publisher: International Union of Crystallography
Additional Information: The Copyright belongs to International Union of Crystallography.
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 21 Apr 2006
Last Modified: 19 Sep 2010 04:25
URI: http://eprints.iisc.ac.in/id/eprint/6384

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