Neutron Diffraction Study on the Magnetic Structure of the Promised Multiferroic Hybrid Perovskite C(ND2)(3)]Cu(DCOO)(3) and Its Centrosymmetric Analogues

Viswanathan, M and Bhat, Shwetha G and Bera, A K and Rodriguez-Carvajal, Juan (2019) Neutron Diffraction Study on the Magnetic Structure of the Promised Multiferroic Hybrid Perovskite C(ND2)(3)]Cu(DCOO)(3) and Its Centrosymmetric Analogues. In: JOURNAL OF PHYSICAL CHEMISTRY C, 123 (30). pp. 18551-18559.

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Abstract

This report presents with one of the rare experimental studies on the magnetic structure of hybrid framework materials, C(ND2)(3)]Me2+(DCOO)(3) (Me = Cu, Mn, and Co), by using neutron powder diffraction. Copper guanidinium formate (CuGF) having a polar structure is a promised multiferroic member of the hybrid perovskite metal guanidinium formates and its Mn/Co analogues possessing a centrosymmetric structure. Previous investigations based on ab initio calculations have suggested that CuGF is a multiferroic whose magnetic space groups are assignable either to Pn'a'2(1) or Pna'2(1)'. Our neutron experiments concurrently reject the Pna'2(1)' possibility and suggest the magnetic structure of CuGF as either Pna2(1) or Pn'a'2(1), with both exhibiting ``Type-A'' magnetic ordering, free from ferromagnetic ordering along the polar-axis, with spins lying in the ab plane. In contrast to CuGF, its centrosymmetric analogues Mn/CoGF are found to display ``Type-G'' magnetic ordering, with their spins aligned along the b and c axis, respectively. The in-depth evaluation of magnetic structure of the metal guanidinium formate frameworks could be helpful in the understanding and designing of the magnetic functionalities of multiferroic hybrid perovskites and could provide an encouraging platform for the improvement of ab initio studies.

Item Type:	Journal Article
Publication:	JOURNAL OF PHYSICAL CHEMISTRY C
Publisher:	AMER CHEMICAL SOC
Additional Information:	copyright for this article belongs to AMER CHEMICAL SOC
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	16 Sep 2019 09:45
Last Modified:	16 Sep 2019 09:45
URI:	http://eprints.iisc.ac.in/id/eprint/63530

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