Encapsulation of paramagnetic $3d^1$-vanadium(IV) in an antiferromagnetically coupled dodecanuclear copper(II) cage

Mukherjee, Arindam and Nethaji, Munirathinam and Chakravarty, Akhil R (2003) Encapsulation of paramagnetic $3d^1$-vanadium(IV) in an antiferromagnetically coupled dodecanuclear copper(II) cage. In: Chemical Communications (24). pp. 2978-2979.

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Abstract

A mixed metal cluster $[Cu_{12}VO_5L_6]$ of a pentadentate Schiff base $(H_3L)$ containing vanadium(IV) in a dodecanuclear copper(II) cage is prepared by vanadyl templated self assembly of dicopper(II) precursor and the structurally characterized complex shows antiferromagnetic coupling involving copper(II) centers, which leads close to diamagnetism for the Cu(II) cage below 40 K in the presence of an encapsulated paramagnetic $3d^1-V(IV)$ atom.

Item Type:	Journal Article
Publication:	Chemical Communications
Publisher:	Royal Society of Chemistry
Additional Information:	The Copyright belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	19 Apr 2006
Last Modified:	19 Sep 2010 04:25
URI:	http://eprints.iisc.ac.in/id/eprint/6334

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