Enantiospecific syntheses of oxacyclodecanes from carvone via mild Lewis acid mediated etherifcation

Srikrishna, Adusumilli and Satyanarayana, Gedu (2019) Enantiospecific syntheses of oxacyclodecanes from carvone via mild Lewis acid mediated etherifcation. In: INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 58 (3, B). pp. 353-361.

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Abstract

An efficient enantiospecific syntheses of oxatri-/tetra-cyclodecanes have been accomplished starting from (R)-carvone. A mild Lewis acid (BF3.OEt2) mediated intramolecular etherification is used as the key step. Structurally aesthetic tri- and tetracyclic ethers have been synthesized.

Item Type:	Journal Article
Publication:	INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
Publisher:	NATL INST SCIENCE COMMUNICATION & INFORMATION RESOURCES-NISCAIR
Additional Information:	Copyright of this article belongs to NISCAIR-CSIR, India
Keywords:	(R)-Carvone; terpenes; cyclic ethers; Lewis acid; etherification
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	27 May 2019 05:50
Last Modified:	25 Sep 2022 06:06
URI:	https://eprints.iisc.ac.in/id/eprint/62613

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