Boron-Catalyzed Carbonate Functionality Transfer Reaction

Rao, Santhosh and Ashwathappa, Puneeth Kumar Someswara and Prabhu, Kandikere Ramaiah (2019) Boron-Catalyzed Carbonate Functionality Transfer Reaction. In: ASIAN JOURNAL OF ORGANIC CHEMISTRY, 8 (3). pp. 320-323.

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Abstract

A carbene transfer reaction has been studied to understand the nature of the tris(pentafluorophenyl)borane stabilized donor-acceptor carbene. For this, a carbonate (or dicarbonate) molecule has been employed resulting in an overall carbonate functionality transfer. The results show that the diazo-derived carbenic carbon displays an electrophilic character. This also presents an opportunity to develop future carbene transfer reactions using a multitude of unconventional nucleophiles with the tris(pentafluorophenyl)borane catalyst.

Item Type:	Journal Article
Publication:	ASIAN JOURNAL OF ORGANIC CHEMISTRY
Publisher:	WILEY-V C H VERLAG GMBH
Additional Information:	copyright for this article belongs to WILEY-V C H VERLAG GMBH
Keywords:	boranes; diazo compounds; carbenes; carbonates; nucleophiles
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	27 May 2019 07:30
Last Modified:	27 May 2019 07:30
URI:	http://eprints.iisc.ac.in/id/eprint/62379

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