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The aryne Sommelet-Hauser rearrangement

Roy, T and Gaykar, RN and Bhattacharjee, S and Biju, AT (2019) The aryne Sommelet-Hauser rearrangement. In: Chemical Communications, 55 (20). pp. 3004-3007.

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Official URL: https://doi.org/10.1039/C9CC00629J


An aryne induced transition-metal-free and mild Sommelet-Hauser rearrangement of tertiary benzylamines for the synthesis of α-aryl amino acid derivatives in moderate to good yields is presented. Unlike the conventional Sommelet-Hauser rearrangement of ammonium salts, the methodology developed herein requires neither harsh conditions nor strong bases. Moreover, a temperature dependent switchable selectivity for the Sommelet-Hauser and Stevens 1,2 rearrangements has been observed. © The Royal Society of Chemistry.

Item Type: Journal Article
Publication: Chemical Communications
Publisher: Royal Society of Chemistry
Additional Information: Copyright for this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 09 Apr 2019 05:15
Last Modified: 25 Aug 2022 07:10
URI: https://eprints.iisc.ac.in/id/eprint/62040

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