Magnetic ground state of the multiferroic hexagonal LuFeO3

Suresh, Pittala and Laxmi, Vijaya K and Bera, AK and Yusuf, SM and Chittari, Bheema Lingam and Jung, Jeil and Kumar, Anil PS (2018) Magnetic ground state of the multiferroic hexagonal LuFeO3. In: PHYSICAL REVIEW B, 97 (18).

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Abstract

The structural, electric, and magnetic properties of bulk hexagonal LuFeO3 are investigated. Single phase hexagonal LuFeO3 has been successfully stabilized in the bulk form without any doping by sol-gel method. The hexagonal crystal structure with P6(3)cm space group has been confirmed by x-ray-diffraction, neutron-diffraction, and Raman spectroscopy study at room temperature. Neutron diffraction confirms the hexagonal phase of LuFeO3 persists down to 6 K. Further, the x-ray photoelectron spectroscopy established the 3+ oxidation state of Fe ions. The temperature-dependent magnetic dc susceptibility, specific heat, and neutron-diffraction studies confirm an antiferromagnetic ordering below the Neel temperature (T-N) similar to 130 K. Analysis of magnetic neutron-diffraction patterns reveals an in-plane (ab-plane) 120 degrees antiferromagnetic structure, characterized by a propagation vector k = (0 0 0) with an ordered moment of 2.84 mu(B)/Fe3+ at 6 K. The 120 degrees antifferomagnetic ordering is further confirmed by spin-orbit coupling density functional theory calculations. The on-site coulomb interaction (U) and Hund's parameter (J(H)) on Fe atoms reproduced the neutron-diffraction Gamma(1) spin pattern among the Fe atoms. P-E loop measurements at room temperature confirm an intrinsic ferroelectricity of the sample with remnant polarization P-r similar to 0.18 mu(C) cm(2). A clear anomaly in the dielectric data is observed at similar to T-N revealing the presence of magnetoelectric coupling. A change in the lattice constants at T-N has also been found, indicating the presence of a strong magnetoelastic coupling. Thus a coupling between lattice, electric, and magnetic degrees of freedom is established in bulk hexagonal LuFeO3.

Item Type:	Journal Article
Publication:	PHYSICAL REVIEW B
Publisher:	AMER PHYSICAL SOC, ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA
Additional Information:	Copy right of this article belong to AMER PHYSICAL SOC, ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	13 Jun 2018 15:25
Last Modified:	25 Feb 2019 11:04
URI:	http://eprints.iisc.ac.in/id/eprint/60011

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